(2-{[1,1-BIS(HYDROXYMETHYL)-2-OXIDOETHYL]IMINOMETHYL}-4-CHLOROPHENOLATO-κ3O,N,O′)DIBUTYLTIN(IV)

(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenolato-κ3O,N,O′)dibutyltin(IV)

(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenolato-κ3O,N,O′)dibutyltin(IV)

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In the title compound, [Sn(C4H9)2(C11H12BrNO4)], the Schiff base ligand T-Shirt chelates to the SnIV atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at the SnIV atom [C—Sn—C = 129.92 (9)°].The remaining methylenehydroxy groups engage in O—H.

O hydrogen bonding with the O atoms Bronzer of adjacent molecules, leading to infinite supramolecular chains propagating in [001].

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